lemon juice — 5 ml for every 5 ml white vinegar (1 tsp)
Both are acidic enough to react fully with the bicarb soda, and in a sweet batter the small amount of apple or lemon flavour bakes into the background.
You're whisking egg whites and sugar for a pavlova or meringue and the recipe adds a teaspoon of vinegar.
lemon juice — 5 ml for every 5 ml white vinegar (1 tsp)
Both supply the acid that helps the egg-white foam hold its structure and give the pavlova its soft centre, and both are pale enough to keep the shell white.
You're making pickles, chutney or relish to store in the pantry, following a tested recipe.
These vinegars match the acetic acid that does the preserving, but only if the label says at least 5% acidity, so check before you start; white wine vinegar keeps the brine clearer, while apple cider vinegar tints it slightly amber.
You're making quick pickled onions, cucumbers or a slaw that will live in the fridge and be eaten within a week or two.
rice vinegar — 250 ml for every 250 ml white vinegar
Here the vinegar is there for sharpness rather than long-term preserving, so milder rice vinegar works well; if yours is seasoned, leave out some of the sugar and salt in the brine.
You're whisking up a vinaigrette, a marinade or a sauce that needs a sharp edge to cut through oil or richness.
All three supply the acidity that balances fat and sweetness; white wine vinegar stays closest to the neutral flavour, while red wine vinegar suits robust dressings and meat marinades where a pink tint does not matter.
You're stirring vinegar into milk to make a stand-in for buttermilk for scones, pancakes or a cake.
lemon juice — 15 ml for every 15 ml white vinegar (3 tsp)
Either acid thickens and curdles the milk slightly in 5–10 minutes and then reacts with the bicarb soda in the recipe, and neither flavour shows once baked.
What White Vinegar does in a recipe
acidity · primary — Its acetic acid sharpens dressings, marinades and sauces and balances sweetness and fat without adding any other flavour.
preserving · primary — At 4–6% acetic acid it lowers the pH of pickles and chutneys far enough to stop spoilage organisms growing.
leavening · secondary — It reacts with bicarbonate of soda to release carbon dioxide, lifting cakes, pancakes and eggless batters.
structure · secondary — Acid helps egg whites hold their foam in meringue and pavlova and makes poached egg whites set faster and tighter.
flavour · secondary — It tastes of sharp acid and nothing else and is colourless, so it keeps pickles and light sauces clear and lets other flavours show.
Its citric acid is strong enough to activate bicarb soda, sour milk and stabilise egg whites, though it adds lemon flavour and is not a safe swap for shelf-stable pickles.
Covers
acidity, leavening, structure
Misses
preserving, flavour
Taste
A fresh citrus flavour replaces the neutral sourness, which is barely noticeable in baked goods.
Texture
No change to texture.
Looks
Fresh juice can make sauces slightly cloudy.
Best for
cakes with bicarb soda, homemade buttermilk, pavlova and meringue
It matches the acidity for pickling and leavening, but brown malt vinegar brings a strong malty, yeasty flavour and dark colour, and it contains gluten.
Covers
acidity, preserving, leavening
Misses
flavour, structure
Taste
A pronounced malty, savoury flavour like fish-and-chip vinegar.
Its acidity covers dressings, marinades and leavening, but the wine flavour and colour show in anything pale.
Covers
acidity, leavening
Misses
flavour, structure, preserving
Taste
A fruity, winey sourness that suits robust dressings and marinades.
Texture
No change to texture.
Looks
Gives pickles, meringue and light sauces a pink or purple tint.
Best for
vinaigrettes, meat marinades, red cabbage
Dairy-freeVeganGluten-freeNut-free
Tried this swap? How did it work?
Commonly tried, but skip these
People reach for these, and they let you down.
balsamic vinegar
Skip it
People reach for it because it is often the only vinegar in the cupboard, but its sugar and dark colour stain pickles and meringue, muddy light sauces and make pickling brine taste sweet and heavy.
Tried this swap? How did it work?
When to buy the real thing
You're bottling pickles or chutney to keep in the pantry and the only alternatives you have are lemon juice, homemade vinegar or a vinegar with no acidity shown on the label.
Instead: Buy a bottle of white vinegar or another vinegar labelled at least 5% acidity, or make the recipe as a fridge pickle and eat it within a couple of weeks.
You're cooking for someone with coeliac disease and the only replacement in the cupboard is brown malt vinegar.
Instead: Use lemon juice or a wine or cider vinegar for that dish, or buy white vinegar, because malt vinegar is made from barley and contains gluten.
You're pickling a large batch where the brine needs to stay clear and colourless, such as white pickled onions, and you only have malt, red wine or balsamic vinegar.
Instead: Buy white vinegar, which is cheap in large bottles, rather than accept a brown or pink brine and a strong competing flavour.
Rescue a swap gone wrong
Your cake or pancakes came out dense and flat with a soapy or metallic aftertaste.
Why: Not enough acid reached the bicarb soda, either because less substitute went in or because the batter sat too long before baking, so unreacted bicarb was left behind.
Can't be fixed — next time: This can't be fixed once baked; next time use the same volume of substitute as the vinegar, mix it in last and get the batter into the oven straight away.
Your pickles or brine have turned brown, amber, pink or cloudy.
Why: Malt, red wine, balsamic or apple cider vinegar carries its own colour, and fresh lemon juice can cloud a brine.
Can't be fixed — next time: The colour can't be removed but the pickles are fine to eat if the vinegar was strong enough; next time use white wine vinegar for clear pickles.
Your dressing or slaw tastes too sweet and salty and not sharp enough.
Why: Seasoned rice vinegar was used, and it already contains sugar and salt on top of what the recipe adds.
Fix: Add a squeeze of lemon juice or a little more vinegar to bring back the sharpness, and add oil or more vegetables to dilute the salt.
Your dressing or soured milk tastes harsher and more sour than expected.
Why: An Australian 20 ml tablespoon was used for a recipe written with 15 ml tablespoons, so about a third more acid went in.
Fix: Balance a dressing with more oil or a pinch of sugar, and add a little more milk to soured milk; next time measure 15 ml for each tablespoon in UK, NZ, US or Canadian recipes.
Key numbers
Acetic acid
4–6%Most supermarket white vinegar sits in this range, but the figure varies by brand and country, so check the label.
Water
about 94–96%Apart from the acetic acid it is almost entirely water, which is why it adds no body or sweetness.
pH
2–3This is acidic enough to activate bicarbonate of soda and to preserve pickles.
Acidity for tested pickling recipes
at least 5%Many tested pickling and bottling recipes assume vinegar of at least 5% acidity, so any substitute for shelf-stable pickles needs to match that on its label.
Differences between countries
Sold as spirit vinegar or distilled malt vinegar (United Kingdom)
In the UK, clear vinegar is often labelled spirit vinegar or distilled malt vinegar rather than white vinegar, and both do the same job in pickles and baking. Brown malt vinegar is the one most kitchens keep for chips, so check you have the clear bottle before pickling.
Distilled malt vinegar starts from barley (United Kingdom)
Distilled malt vinegar is made from malted barley, so check the label or the manufacturer's guidance if you are cooking for someone who must avoid gluten.
Applies to Australia
Cleaning vinegar is not for food (Australia, United Kingdom, New Zealand, United States, Canada)
Some vinegars sold for household cleaning are stronger than food vinegar and are not intended for cooking. Buy the bottle from the food aisle and check that the label shows the acidity.
Applies to Australia
20 ml tablespoon (Australia)
An Australian tablespoon holds 20 ml, while UK, NZ, US and Canadian tablespoons hold 15 ml. In dressings and soured milk, using an Australian tablespoon for an overseas recipe adds about a third more acid.
Large jugs (United States)
In the US, distilled white vinegar is commonly sold in large jugs as well as small bottles, which makes it cheap to buy for big pickling batches.
Where to buy it
Applies to Australia
Australia · easy to find
condiment and vinegar aisle
It is usually sold next to the other vinegars and oils, often in large bottles that are useful for pickling.
United Kingdom · easy to find
condiment and pickling aisle
Look for spirit vinegar or distilled malt vinegar, which are the usual UK labels for clear vinegar.
New Zealand · easy to find
condiment and vinegar aisle
It is usually shelved with the other vinegars and oils.
United States · easy to find
condiment and vinegar aisle
It is usually labelled distilled white vinegar and comes in bottles and large jugs.
Canada · easy to find
condiment and vinegar aisle
It is usually shelved with the other vinegars and oils.
What is White Vinegar called in other countries?
distilled white vinegarspirit vinegardistilled vinegardistilled malt vinegar
Measurements differ too, not just names: the kitchen conversion chart covers cups, spoons and oven temperatures across these countries.
Questions people ask
Is white vinegar the same as white wine vinegar?
No, they are different products. White vinegar is made from a neutral distilled alcohol and tastes of sharp acid alone, while white wine vinegar is made from wine and has a softer, slightly fruity flavour. They can be swapped one for one in most recipes, including pickles, as long as the label shows at least 5% acidity.
Is spirit vinegar the same as white vinegar?
Yes, spirit vinegar is the usual UK name for clear white vinegar. Distilled malt vinegar is also clear and can be used the same way, but it is made from malted barley, so check the label if you are cooking gluten-free.
Can I leave the vinegar out of a pavlova?
You can, but the pavlova is more likely to weep, crack or lose its soft, marshmallowy centre. The acid helps the egg-white foam hold together as it bakes, so lemon juice or white wine vinegar in the same amount is a better choice than leaving it out.
Can I use cleaning vinegar for cooking or pickling?
No, use vinegar sold for food. Cleaning vinegar can be stronger than food vinegar and is not intended to be eaten, so it is not a safe swap in pickles, dressings or baking.
How much is a tablespoon of vinegar in a UK or US recipe?
A tablespoon in UK, NZ, US and Canadian recipes is 15 ml. An Australian tablespoon is 20 ml, so measuring with one adds about a third more vinegar, which is enough to make a dressing or soured milk noticeably sharper. Use a 15 ml measure or three 5 ml teaspoons for those recipes.
Is white vinegar gluten-free?
White vinegar is generally treated as gluten-free, even when it is made from grain, because the gluten does not carry through distillation. Brown malt vinegar is different because it is made from barley and contains gluten, so do not use it as a swap for someone with coeliac disease.
Where White Vinegar comes from
White vinegar is made by fermenting a dilute distilled alcohol with acetic acid bacteria, which turn the alcohol into acetic acid. The alcohol is usually made from grain, sugar cane or molasses, and the finished vinegar is diluted with water to the strength shown on the label.
White Vinegar is usually dairy-free, vegan, gluten-free, nut-free — check the label, and see the disclaimer.